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Gaussian inc 09, revision d.01
09, Revision D.01, supplied by Gaussian inc, used in various techniques. Bioz Stars score: 90/100, based on 1 PubMed citations. ZERO BIAS - scores, article reviews, protocol conditions and more
https://www.bioz.com/product/09%2C+revision+d%2E01/09++revision+d+01/pm40586646-426-8-10
Average 90 stars, based on 1 article reviews
09, revision d.01 - by Bioz Stars, 2026-09
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Article Title: Supporting Information Reversible Dihydrogen Activation and Catalytic H/D Exchange with Group 10 Heterometallic Complexes
Article Snippet: B.; Ortiz, J. V.; Cioslowski, J.; Fox, D. J. Gaussian 09, Revision D.01; Gaussian, Inc., Wallingford, CT, USA (2009).

Article Title: Delicate Tuning of Reaction Thermodynamics via Formation of Bimetal Phenoxide: Synthesis, Structure, and Hydrogen Storage Performance
Article Snippet: Arene-cycloalkane pairs are promising for hydrogen storage but often encounter unfavorable thermodynamic and kinetic issues in hydrogenation and dehydrogenation.. A recent strategy to circumvent thermodynamic constraints involves introducing electrondonating alkali and alkaline earth metals into arene-cycloalkane pairs.. However, excessive aromatic stabilization during the metalation of single-ring arene-cycloalkane leads to immoderate thermodynamic tuning in monometal organic compounds.

Article Title: Efficiency of Photodissociation of Carbonyl Ligand in Ruthenium Monocarbonyl Bipyridine Complexes: Effect of Isomeric Structures and Ligands.
Article Snippet: Photoactivated CO-releasing molecules have potential medical applications. trans(Cl,Cl)-[Ru(bpy)(CO)2Cl2] (bpy = 2,2′-bipyridine) efficiently releases the first CO ligand (∼100% quantum yield), but the second CO dissociation is inefficient, and its precise quantum yield remains undetermined.. Photodissociation of trans(Cl,Cl)-[Ru(bpy)(CO)2Cl2] yielded two monocarbonyl complexes, cis(Cl,Cl),trans(Cl,CH3CN)-[Ru(bpy)(CO)(CH3CN)Cl2] and trans(Cl,Cl)-[Ru(bpy)(CO)(CH3CN)Cl2], as the major and minor stereoisomeric products, respectively.. The apparent quantum yields for the second CO dissociations were 0.56% and 0.78% for cis(Cl,Cl),trans(Cl,CH3CN)and trans(Cl,Cl)-isomers, respectively.

Article Title: Double Sb-N Coordination Enables Record-High Birefringence in UV-Transparent Crystals.
Article Snippet: Achieving high birefringence in ultraviolet (UV)-transparent crystals has remained a significant challenge due to the absence of systematic design methodologies.. Herein, we present a novel organic–inorganic coordination strategy that combines π -conjugated organic ligands ([C12H8N2]) with inorganic Sb-based polyhedra featuring stereochemically active lone pairs.. This approach facilitates the formation of the first coplanar double SbN coordination framework, enabling the synthesis of two new birefringent hybrid crystals: (C12H8N2)SbF2(H2PO3) (PNSP) and (C12H8N2)SbF3 (PNSF).

Article Title: 1,2-Allenic Ketone-Based Fluorogenic Probes for Imaging of S-Sulfinylation in Living Cells.
Article Snippet: Cysteine S-sulfinylation is an important oxidative post-translational modification on proteins that regulates a variety of cell and protein functions.. Aberrant S-sulfinylation contributes to a range of human pathologies, such as cancer and cardiovascular disease.. However, efforts to elucidate the roles of S-sulfinylation in physiology and disease have been hampered due to the lack of methodology for the selective and direct monitoring of this modification in living cells.

Article Title: Mechanistic Insights into a Palladium-Catalyzed Quaternary Carbon-Editing Strategy: A DFT Study.
Article Snippet: Direct editing of quaternary carbon remains highly challenging.. In this study, we computationally investigated a palladium-catalyzed quaternary carbon-editing strategy using density functional theory (DFT) to elucidate its principal characteristics and address key mechanistic issues.. A quaternary carbon-editing mechanism driven by sequential Pd migration was established.

Functional Assay:

Article Title: Proline-Aromatic Sequences Stabilize Turns via C-H/π Interactions in Both cis -Proline and trans -Proline.
Article Snippet: In proteins, proline-aromatic sequences exhibit increased frequencies of cis-proline amide bonds, via proposed C−H/ π interactions between the aromatic ring and either the proline ring or the backbone C−Hα of the residue prior to proline.. However, previous bioinformatics studies on proteins and experiments on proline-aromatic sequences in peptides have not revealed a clear correlation between the electronic properties of the aromatic ring and the population of cis-proline.. An investigation of the effects of aromatic residue on the conformation of proline-aromatic sequences was conducted using three approaches: NMR spectroscopy in model peptides of the sequence Ac-TGPAr-NH2 (Ar = encoded and unnatural aromatic amino acids); bioinformatics analysis of structures in proline-aromatic sequences in the PDB; and quantum computational investigations.

Spectroscopy:

Article Title: Proline-Aromatic Sequences Stabilize Turns via C-H/π Interactions in Both cis -Proline and trans -Proline.
Article Snippet: In proteins, proline-aromatic sequences exhibit increased frequencies of cis-proline amide bonds, via proposed C−H/ π interactions between the aromatic ring and either the proline ring or the backbone C−Hα of the residue prior to proline.. However, previous bioinformatics studies on proteins and experiments on proline-aromatic sequences in peptides have not revealed a clear correlation between the electronic properties of the aromatic ring and the population of cis-proline.. An investigation of the effects of aromatic residue on the conformation of proline-aromatic sequences was conducted using three approaches: NMR spectroscopy in model peptides of the sequence Ac-TGPAr-NH2 (Ar = encoded and unnatural aromatic amino acids); bioinformatics analysis of structures in proline-aromatic sequences in the PDB; and quantum computational investigations.

Nuclear Magnetic Resonance:

Article Title: LC-MS/MS-Guided Discovery of Sinapic Acid Derivatives from Lepidium sativum Seeds and Their Anti-inflammatory Activity.
Article Snippet: Edible seeds of Lepidium sativum are known for their health-promoting properties.. A total of 17 sinapic acid derivatives, including 12 previously undescribed compounds, were isolated from L. sativum seeds using an LC−MS/MS-guided strategy.. Among them, lepisativutimines A−F (1−6) were identified as rare sinapic acid derivatives featuring a uridine moiety.



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